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Duplex Stainless Steel Pipe for Nuclear Power Cooling Water System

As a clean energy, nuclear power is a major contributor to global carbon emissions reduction, and it can play a greater role in the future. Duplex stainless steel pipe for cooling water system is the future.

The key factor for the safe operation of nuclear power plants is the cooling water piping system. This complex system contains thousands of feet of pipes with diameters ranging from large to small, and its function is to provide reliable water supply for the cooling of nuclear power plant equipment.

There is usually a non-safety-level operating system and a safety-level emergency system. Non-safety-grade piping systems must provide sufficient cooling water for normal cooling of nuclear power equipment. The safety-level system must provide sufficient cooling water to keep the reactor under control and shut down safely in an emergency. The piping materials used in these systems must be resistant to corrosion by cooling water throughout the life of the equipment.

Depending on the location of the nuclear power plant, the types of cooling water range from relatively clean fresh water to polluted seawater. Therefore, the degree of corrosion of pipeline materials varies greatly. Experience has shown that as the system ages, various corrosion problems may occur. If not solved, it will cause damage to the system and prevent it from providing the required cooling water.


Materials and problems of cooling water system

Leakage caused by scaling (blocking) and corrosion of the cooling water pipe system is the most common problem. The following conditions often lead to fouling: accumulation of sediment, marine organisms (biofouling), accumulation of corrosion products, and clogging of foreign bodies.

Scaling inside carbon steel pipes
Scaling inside carbon steel pipes

Leakage problems are usually caused by microbiological corrosion (MIC). MIC is a very aggressive form of corrosion caused by certain microorganisms in the water. Carbon steel and low-alloy stainless steel often experience this form of corrosion.

Most nuclear power plants operating in North America used carbon steel piping systems, sometimes coated or lined with cement or rubber. Due to reliability issues, continuous monitoring is necessary and maintenance costs are high.

As a result, many units have replaced carbon steel pipes with more corrosion-resistant materials. In order to meet the design life of the new nuclear power station of more than 60 years, the use of better-performing materials will be considered.

Stainless steel has always been considered a viable option for constructing new water supply piping systems and repairing or replacing existing carbon steel systems.

The commonly used stainless steel in the pipeline upgrade program is 304L, 316L or 6% Mo stainless steel. The performance and price gap between 316L and 6% Mo stainless steel is large.

If the cooling medium is untreated water, which is highly corrosive and has the risk of microbial corrosion, 304L and 316L are not appropriate choices.

Therefore, nuclear power plants have to upgrade to 6% Mo stainless steel or accept the high maintenance costs of carbon steel systems. Some nuclear power plants still use carbon steel lined pipes because of lower initial costs.

The chemical composition range of stainless steel commonly used in industrial water supply piping systems
The chemical composition range of stainless steel commonly used in industrial water supply piping systems

2205 duplex stainless steel proved to be a good choice

Duke Energy’s Catawba Nuclear Power Plant in South Carolina, USA is the first nuclear power plant to use duplex 2205 (UNS S32205) duplex stainless steel in its system.

This grade from stainless steel pipe fittings supplier contains about 3.2% molybdenum, which improves corrosion resistance and is significantly better than 304L and 316L stainless steel.

The piping system that transports make-up water to the cooling tower of the main condenser. The above-ground carbon steel lined pipes are replaced with 2205 duplex stainless steel pipes.

Large diameter 2205 duplex stainless steel pipe installed in nuclear power plant
Large diameter 2205 duplex stainless steel pipe installed in nuclear power plant

After the pipeline was used for 500 days, the system was thoroughly inspected. During the inspection, no signs of scaling or corrosion were found. The performance of 2205 duplex stainless steel is very good.

For more than ten years since installation, 2205 stainless steel pipes have been performing well. Based on this experience, Duke Energy has used 2205 duplex stainless steel piping in other parts of its system.

Internal corrosion of 2205 pipeline after 500 days
Internal corrosion of 2205 pipeline after 500 days

Now, there is one more choice in duplex stainless steel pipe for cooling water system. The successful application of duplex stainless steel can reduce maintenance costs, reduce downtime and ensure the safe operation of nuclear power plants.

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